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- W2063580891 abstract "Cationic rhenium tricarbonyl complexes with three N-alkylimidazole ligands undergo deprotonation of the central CH group upon reaction with 1 equiv of KN(SiMe3)2. For the tris(N-methylimidazole) complex, the metal fragment shifts from N to C, leaving an NHC complex with a nonsubstituted N atom. For compounds with at least one N-mesitylimidazole ligand, the intramolecular attack of the deprotonated carbon onto the central carbon of an N-mesitylimidazole ligand results in ring opening of the latter." @default.
- W2063580891 created "2016-06-24" @default.
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- W2063580891 date "2008-09-20" @default.
- W2063580891 modified "2023-10-17" @default.
- W2063580891 title "From <i>N</i>-Alkylimidazole Ligands at a Rhenium Center: Ring Opening or Formation of NHC Complexes" @default.
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- W2063580891 doi "https://doi.org/10.1021/ja805888f" @default.
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