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- W2063582922 abstract "Reaction of Li[C5H5B–Ph] with [RhCl(C2H4)2]2 gives [C5H5B–Ph]Rh(C2H4)2 1 in 91% yield; similarly, Li[C5H5B–NMe2] with [RhCl(C2H4)2]2 gives [C5H5B–NMe2]Rh(C2H4 )2 2 in 85% yield; single crystal X-ray analysis studies of 1 and 2 show a molecular geometry analogous to those of the Cp and Cp* complexes; the use of 1 and 2 in promoting alkane boration was evaluated against the activity of Cp*Rh(C2H4)2 3; the boratabenzene complexes 1 and 2 show faster initiation, but yield less thermally stable catalysts than 3." @default.
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- W2063582922 date "2001-01-01" @default.
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- W2063582922 title "Synthesis, characterization and C–H activation reactivity of bis(ethylene) boratabenzene rhodium complexes" @default.
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- W2063582922 doi "https://doi.org/10.1039/b009246k" @default.
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