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- W2063587788 abstract "Abstract A stopped flow technique has been used to investigate the mechanism and kinetics of reaction of Mn III with 1,2-dihydroxybenzene in aqueous perchlorate solutions. The acidity range investigated was 0.50 ≦ [HClO 4 ]≦3.00 M, at ionic strength I = 3.0 M, and at 25.0, 18.0 and 12.0° C. The oxidation product, o-benzoquinone, is obtained according to a stoichiometry given by: 2Mn III +H 2 cat→2Mn II +qno+2H + The reaction rate was first order in both reactants and the variation of the rate on acidity pointed out that the overall reaction takes place through two paths, one independent and one dependent on [H + ] −1 . These paths are discussed in terms of alternative inner or outer-sphere mechanisms due to the lack of evidence of intermediate complexes formation." @default.
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- W2063587788 date "1975-01-01" @default.
- W2063587788 modified "2023-09-28" @default.
- W2063587788 title "Redox reaction of 1,2-dihydroxybenzene with Mn(III) in aqueous perchlorate media. Kinetics and mechanism" @default.
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- W2063587788 doi "https://doi.org/10.1016/s0020-1693(00)89836-9" @default.
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