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- W2063618085 abstract "Three novel pentacoordinate silicon compounds with SiO5 skeletons containing SiOH or SiOSi groups were synthesized: triethylammonium bis[benzilato(2−)-O1,O2]hydroxosilicate (1; isolated as rac-1), anilinium bis[benzilato(2−)-O1,O2]hydroxosilicate [2; isolated as a conglomerate consisting of (Λ)-2·THF and (Δ)-2·THF], and anilinium tetrakis[benzilato(2−)-O1,O2]-μ-oxo-disilicate (3; isolated as rac-3·2CH3CN). The λ5Si-hydroxosilicate and λ5Si,λ5Si‘-μ-oxo-disilicate anions of these salts formally derive from the pentahydroxosilicate(1−) anion [Si(OH)5]- and its anhydride [(HO)4Si−O−Si(OH)4]2-, respectively. All compounds were characterized in solution (1H, 13C, and 29Si NMR) and in the solid state (29Si VACP/MAS NMR, crystal structure analyses)." @default.
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- W2063618085 date "2000-08-18" @default.
- W2063618085 modified "2023-10-11" @default.
- W2063618085 title "Pentacoordinate Silicon Compounds with <i>Si</i>O<sub>5</sub> Skeletons Containing SiOH or SiOSi Groups: Derivatives of the Pentahydroxosilicate(1−) Anion [Si(OH)<sub>5</sub>]<sup>-</sup> and Its Anhydride [(HO)<sub>4</sub>Si−O−Si(OH)<sub>4</sub>]<sup>2</sup><sup>-</sup>" @default.
- W2063618085 cites W2011581133 @default.
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- W2063618085 doi "https://doi.org/10.1021/ja000637i" @default.
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