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- W2063633312 abstract "This work reports the preparation of glass-like, environmentally-friendly, cerium-based coatings for active corrosion protection of aluminium and magnesium alloys. It describes the production of cerium sol–gel sols from cerium nitrate and their deposition by immersion and automatic spray onto aluminium and magnesium alloys to produce uniform coatings with amorphous (glass-like) structures (Ce x O y ). The coatings have been characterised by profilometry, scanning electron microscopy (SEM), spectral ellipsometry and UV–visible, in order to analyse the structure and density of the glass-like cerium coatings as well as their redox ratio Ce 4+ /Ce 3+ as a function of pH and sintering temperature . Finally, electrochemical measurements (EIS) and standard corrosion tests (neutral salt spray, filiform corrosion , immersion–emersion test and adhesion on embossing and T-bend test) have been performed to study the corrosion behaviour of the cerium glass-like coatings on aluminium and magnesium alloys. EIS measurements confirm the healing or blocking of the defects by the corrosion inhibiting species. Excellent corrosion protection is provided by cerium glass-like coatings, satisfying the most demanding industrial requirements. ► New glass-like Ce x O y coatings for active corrosion protection of Al and Mg alloys. ► Scale up of sols and deposition by automated spray completed with organic paints. ► Suitable protection of complete system confirmed by standard corrosion tests. ► Eco-friendly Ce x O y coatings are promising candidates to replace chromium coatings." @default.
- W2063633312 created "2016-06-24" @default.
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- W2063633312 date "2011-10-01" @default.
- W2063633312 modified "2023-10-16" @default.
- W2063633312 title "Glass-like CexOy sol–gel coatings for corrosion protection of aluminium and magnesium alloys" @default.
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- W2063633312 doi "https://doi.org/10.1016/j.surfcoat.2011.07.006" @default.
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