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- W2063657524 abstract "The title compound, ent-1, the non-natural enantiomeric form of the lycorenine-type alkaloid (-)-clividine (1), has been prepared using the enantiomerically pure (ee >99.8%) cis-1,2-dihydrocatechol 3 as starting material. A key feature associated with the closing stages of the synthesis involved the diastereoselective addition of a nitrogen-centered radical onto a pendant cyclohexene to establish the cis-fused D-ring and the required stereochemistry at C11b in the final product ent-1." @default.
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- W2063657524 date "2011-07-11" @default.
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- W2063657524 title "A Chemoenzymatic Total Synthesis of (+)-Clividine" @default.
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- W2063657524 doi "https://doi.org/10.1021/jo201005d" @default.
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