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- W2063659851 abstract "Abstract The vapor-phase absorption spectrum of propiolyl fluoride HCCCOF and deuterio-propiolyl fluoride has been examined under medium resolution in the region from 303 to 260 nm. While considerable vibrational structure is evident, all bands are found to be rotationally diffuse. The electronic transition is identified as the singlet-singlet π ∗ ← n transition analogous to the 382-nm system of propynal. The evidence for a nonplanar excited-state geometry is discussed. The principal excited-state vibrational frequencies identified are 158 (ν′9), 396 (ν′8), and 1222 cm−1 (ν′3) for HCCCOF. The corresponding values for DCCCOF are 150, 390, and 1217 cm−1, respectively. The triplet ← singlet system involving the same electron promotion has not been found." @default.
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- W2063659851 date "1980-03-01" @default.
- W2063659851 modified "2023-09-24" @default.
- W2063659851 title "The 290-nm absorption system of propiolyl fluoride" @default.
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- W2063659851 doi "https://doi.org/10.1016/0022-2852(80)90273-8" @default.
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