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- W2063661352 abstract "Absolute rate constants were measured for the reaction CN + CH2O over the temperature range 297–673 K and CN + 1,3,5-trioxane over the range of 297–600 K by the laser photolysis/laser induced fluorescence technique. The rate constants for these reactions can be effectively represented, in units of cm3/s, by: k(CH2O) = 2.82 × 10−19 T2.72 exp(718/T), and k(1,3,5-trioxane) = 1.39 × 10−23 T4.26 exp(1333/T), respectively. Transition state theory calculations were able to fit the temperature dependence of the CN + CH2O rates relatively well. We attempted to correlate the CN reaction rate with CH2O and other molecules which occur through simple abstraction with the corresponding OH reaction rates, yielding only a qualitative linear correlation for a majority of the processes. The reactions which deviated significantly from linearity include those which contain strong dipoles, highlighting the significant role long-range attractive forces play in CN and OH reactions. Using a simple electrostatic potential, cross-sections were determined for reactions with CN. No linear correlation was found between the calculated and experimental cross sections for the majority of the reactions studied. © 1993 John Wiley & Sons, Inc." @default.
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- W2063661352 date "1993-12-01" @default.
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- W2063661352 title "Kinetics of CN radical reactions with formaldehyde and 1,3,5-trioxane" @default.
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- W2063661352 doi "https://doi.org/10.1002/kin.550251210" @default.
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