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- W2063662173 abstract "Abstract Di( tert ‐butyl)sulfur diimide and bis(trimethylsilyl)sulfur diimide were reacted with different metalated amines to form versatile novel multidentate ligand systems with side‐arm donation. Their complexation properties in terms of ligand design, denticity and the cation size are discussed. We report herein the synthesis and structure elucidation of [( t BuN) 2 S{LiMe 2 N(C 6 H 4 )S(N t Bu) 2 } 2 ] ( 1 ), [(Li{Me 2 N(C 6 H 4 )S(NSiMe 3 ) 2 }) 2 ] ( 2 ), [(Li(thf){Me 2 N(C 6 H 4 )S(NSiMe 3 ) 2 }) 2 ] ( 3 ), [(Li{2‐PicS(NSiMe 3 ) 2 }) 2 ] ( 4 ), [(Li{Me 2 N(CH 2 ) 2 N(Me)S(NSiMe 3 ) 2 }) 2 ] ( 5 ), [(Na{Me 2 N(CH 2 ) 2 N(Me)S(NSiMe 3 ) 2 }) 2 ] ( 6 ) and [(K{Me 2 N(C 6 H 4 )S(NSiMe 3 ) 2 }) 2 ] ( 7 )." @default.
- W2063662173 created "2016-06-24" @default.
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- W2063662173 date "2011-07-05" @default.
- W2063662173 modified "2023-10-18" @default.
- W2063662173 title "Novel Multidentate Sulfur-Nitrogen Ligands with Enhanced Complexation Properties" @default.
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- W2063662173 doi "https://doi.org/10.1002/chem.201100614" @default.
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