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• W2063663530 abstract "The (E)-1-ferrocenyl-2-(1-methyl-4-pyridinium)ethylene cation, (E)-FcMPE+, forms a very stable guest−host complex (KCB7 = (1.3 ± 0.5) × 1012 M-1) in aqueous solution with cucurbit[7]uril (CB[7]). The 1H NMR, ES-MS, and UV−visible spectra are consistent with 1:1 {(E)-FcMPE·CB[7]}+ species formation, in which the CB[7] encapsulates the ferrocenylethylene portion of the guest. The reduction potential of the (E)-FcMPE2+/+ couple increases slightly (+0.03 V) in the presence of CB[7], while the rate constant for the oxidation of (E)-FcMPE+ by Co(dipic)2- (dipic2- = 2,6-pyridinedicarboxylate) decreases significantly. UV−visible spectra of (E)-FcMPE+ in the absence and in the presence of CB[7] during photoirradiation demonstrate that the photoisomerization to (Z)-FcMPE+ is fully inhibited and photostabilization of (E)-FcMPE+ is dramatically enhanced upon inclusion in CB[7]." @default.
• W2063663530 created "2016-06-24" @default.
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• W2063663530 date "2006-02-22" @default.
• W2063663530 modified "2023-10-12" @default.
• W2063663530 title "Stabilization of the (<i>E</i>)-1-Ferrocenyl-2-(1-methyl-4-pyridinium)ethylene Cation by Inclusion in Cucurbit[7]uril" @default.
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• W2063663530 doi "https://doi.org/10.1021/om051054q" @default.
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