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• W2063684332 abstract "Of the known trinuclear dipyridylamido complexes of the first-row transition metals, M(3)(dpa)(4)Cl(2) (dpa is the anion of di(2-pyridyl)amine, M = Cr, Co, Ni, Cu), the one-electron-oxidation products of only Cr(3)(dpa)(4)Cl(2) and Co(3)(dpa)(4)Cl(2) have been isolated previously. Here we report one-electron-oxidation products of Ni(3)(dpa)(4)Cl(2) (1) and Cu(3)(dpa)(4)Cl(2) (3): Ni(3)(dpa)(4)(PF(6))(3) (2) and [Cu(3)(dpa)(4)Cl(2)]SbCl(6) (4). While there are no Ni-Ni bonds in 1, the Ni-Ni distances in 2 are 0.15 A shorter than those in 1, very suggestive of metal-metal bonding interactions. In contrast, the oxidation of 3 to 4 is accompanied by a lengthening of the Cu-Cu distances, as expected for an increase in electrostatic charge between positively charged nonbonded metal ions, which is further evidence against Cu-Cu bonding in either 3 or 4. A qualitative model of the electronic structures of all [M(3)(dpa)(4)Cl(2)](n+) (n = 0, 1) compounds is presented and discussed." @default.
• W2063684332 created "2016-06-24" @default.
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• W2063684332 date "2003-03-05" @default.
• W2063684332 modified "2023-10-16" @default.
• W2063684332 title "Oxidation of Ni₃(dpa)₄Cl₂ and Cu₃(dpa)₄Cl₂: Nickel−Nickel Bonding Interaction, but No Copper−Copper Bonds" @default.
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• W2063684332 doi "https://doi.org/10.1021/ic0262740" @default.
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