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Matches in SemOpenAlex for { <https://semopenalex.org/work/W2063695909> ?p ?o ?g. }

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• W2063695909 abstract "The complete conversion of racemic amino acid amides to optically active amino acid derivatives was accomplished via lipase/palladium-catalyzed dynamic kinetic resolution (DKR). In the DKR, a lipase catalyzes the selective acylation of L-substrate in the presence of acyl donor while unreacted D-substrate is isomerized by a Pd nanocatalyst to L-substrate. The DKR reactions provided good yields (80-98%) and high enantiomeric excess (95-98% ee). Interestingly, the DKR reactions of phenylglycine amide in the presence of Z-Gly-OMe or Z-Gly-Gly-OMe yielded optically active di- and tripeptide ." @default.
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• W2063695909 date "2009-11-17" @default.
• W2063695909 modified "2023-10-18" @default.
• W2063695909 title "Synthesis of Optically Active Amino Acid Derivatives via Dynamic Kinetic Resolution" @default.
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• W2063695909 doi "https://doi.org/10.1021/jo902034x" @default.
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