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- W2063729245 abstract "Band-systems of GeCl and GeBr are developed in the regions λ3202-λ2847 and λ3260-λ2946 respectively in heavy-current tube-discharges through continuous flows of GeCl4 and GeBr4 vapours. Each consists of two subsystems of bands degraded towards shorter wave-lengths, the heads being represented approximately by GeCl: ν = {33017.2, 33992.2} + (526.6u' - 0.3u'2) - (408.4u'' - 1.6u''2), GeBr: ν = {32263.4, 33413.4} + (383.7u' - 0.7u'2) - (296.6u'' - 0.9u''2) where u = ν + ½. The systems are probably 2σ → 2π, the lower states, with electronic intervals 975 and 1150 cm-1. respectively, being the ground states of GeCl and GeBr. The electronic intervals δνe, the upper state energies (system-origins) νe, and the vibrational coefficients ωe and xeωe for both electronic states are compared with those of band-systems of other monohalides of group - IV(b) elements. With increasing atomic number and mass of either atom (group-IV(b) or halogen) the expected trend is observed in each case, namely an increase in δνe, and decreases in νe, ωe and xeωe, except for δνe in SiBr and the Pb monohalides; the apparent anomalies are discussed." @default.
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- W2063729245 date "1937-09-01" @default.
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- W2063729245 title "Ultra-violet band-systems of GeCl and GeBr" @default.
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- W2063729245 doi "https://doi.org/10.1088/0959-5309/49/5/309" @default.
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