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- W2063790040 abstract "Strong specific intermolecular interactions generally lead to large deviations from solution ideality, which can be exploited for a variety of separation and reaction processes. Very often extractive distillations, liquid-liquid extractions, and supercritical extractions, especially with cosolvents, are designed so that these types of interactions give high specificity. One designs chromatograph columns and membranes precisely for specific interactions, and engineers exploit these interactions in a variety of other processes ranging from chelation to homogeneous catalysis. This account describes methods for characterizing mathematically the thermodynamics of solutions exhibiting strong interactions, including the more realistic chemical-physical type theories as well as the application of extrathermodynamic methods for the determination of model parameters. 74 refs., 8 figs., 1 tab." @default.
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- W2063790040 date "1993-12-01" @default.
- W2063790040 modified "2023-09-24" @default.
- W2063790040 title "Modeling solutions containing specific interactions" @default.
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- W2063790040 doi "https://doi.org/10.1021/ar00036a003" @default.
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