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- W2063828315 abstract "To probe the structural effects of Group 1 (M = Na, K) and Group 14 (El = Ge(II), Sn(II)) ions on adducts between MCp and MEl(OtBu)3 salts, the metal ions were systematically varied and the solid-state structures of the adducts were studied by single-crystal X-ray methods. KCp maintained its undulating chain structure, albeit decorated with isolated K(THF)2Sn(OtBu)3 units. The initially-linear NaCp chain, however, became intercalated with MEl(OtBu)3 moieties, and the ensuing polymer adopted a zigzag-chain structure. A mixture of KCp and NaGe(OtBu)3 underwent an ion exchange to give NaCp and KGe(OtBu)3, revealing that tridentate [Ge(OtBu)3]− prefers the larger potassium ion to sodium ion." @default.
- W2063828315 created "2016-06-24" @default.
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- W2063828315 date "2014-03-01" @default.
- W2063828315 modified "2023-10-14" @default.
- W2063828315 title "Group 1 cyclopentadienide/group 1,14-tert-butoxide adducts: Ion exchange and coordination polymer formation" @default.
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- W2063828315 doi "https://doi.org/10.1016/j.poly.2013.12.020" @default.
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