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- W2063898446 abstract "Reported herein is the enantioselective conjugate addition of n-butyl to 2-cyclopentenone, 2-cyclohexenone, 2-cycloheptenone and 2-cyclooctenone using scalemic amidocuprates derived from copper(I) iodide, n-butyllithium and a homologous series of 5 scalemic tetraamines referred to as DIMMAP-2 through -6. Cuprates derived from DIMAPP-4 manifest the highest enantioselectivities (up to 78%) and the same sense of enantioselectivity as the MAPP cuprates upon which these new cuprates are based. A previously developed mechanistic proposal has been revised to account for the observations made." @default.
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- W2063898446 date "1994-04-01" @default.
- W2063898446 modified "2023-10-11" @default.
- W2063898446 title "Enantioselective conjugate addition, part V. Synthesis and testing of scalemic tetraamines as chiral cuprate ligands." @default.
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- W2063898446 doi "https://doi.org/10.1016/s0040-4020(01)89378-9" @default.
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