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• W2063904278 abstract "The effect of cationic micelles of cetyltrimethyl ammonium bromide (CTAB) on the observed pseudo-first-order rate constant for the interaction of nickel dipeptide complex [Ni(II)-Gly-Gly]+ with ninhydrin has been studied spectrophotometrically. At constant temperature and pH, increase in the [CTAB] from 0.0 to 60.0 × 10−3 mol dm−3 caused nearly three-fold increase of the rate constant. The micellar catalysis is explained in terms of the pseudophase model. From the observed kinetic data, binding constants of micelle–[Ni(II)-Gly-Gly]+ (K S), and micelle–ninhydrin (K N) are evaluated, respectively, to be 5.3 mol−1 dm3 and 84.0 mol−1 dm3. The role of added inorganic (NaCl, NaBr, Na2SO4) and organic salts (NaBenz, NaSal) on the reaction rate has also been examined." @default.
• W2063904278 created "2016-06-24" @default.
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• W2063904278 date "2008-10-24" @default.
• W2063904278 modified "2023-10-16" @default.
• W2063904278 title "Micelle-Catalyzed Interaction Between [Ni(II)-Gly-Gly]⁺and Ninhydrin" @default.
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• W2063904278 doi "https://doi.org/10.1080/01932690802313030" @default.
• W2063904278 hasPublicationYear "2008" @default.
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