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- W2063924445 abstract "Abstract A deeper analysis and development of the ideas from the previous two articles [Urbanovici and Segal, Thermochim. Acta, 111 (1987) 335; 118 (1987) 65] is presented. Special emphasis is given to the classical change, or better, classical non-isothermal change (CNC), of some isothermal kinetic equations. We shall start from the isothermal differential kinetic equation dα/d t = f(α)k( T )h(α, T ) axiomatically accepted as postulated primary isothermal differential kinetic equation (P-PIDKE). A critical examination of the correct and incorrect procedures to derive non-isothermal kinetic equations using CNC is presented. The particular isothermal differential kinetic equation dα/d t = A f(α)e − E/RT will be considered as example. A new formulation of the model of the infinitesimal isothermal portions (MIIP), as well as discussions concerning the difference between non-isothermal kinetics with constant heating rate and non-isothermal kinetics with variable heating rates are presented. The article concludes with the necessity to use PIDKE or alternatively MIIP for deriving correct non-isothermal kinetic equations." @default.
- W2063924445 created "2016-06-24" @default.
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- W2063924445 date "1988-03-01" @default.
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- W2063924445 title "Some problems concerning the mathematical theory of non-isothermal kinetics. III. the classical non-isothermal change of some equations derived from the rate equation dα/dt = f(α)k(T)h(α, T) accepted as postulated primary isothermal differential kinetic equation" @default.
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- W2063924445 doi "https://doi.org/10.1016/0040-6031(88)87227-7" @default.
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