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- W2063953793 abstract "Abstract Malijevska, I. and Chýlkova, K., 1993. Vapor-liquid equilibrium in the binary system ethanoic acid(1)-4-methyl-2-pentanone(2). Fluid Phase Equilibria , 87: 365-377. Vapor-liquid equilibria and excess molar volumes were determined for the binary system ethanoic acid-4-methyl-2-pentanone at 101.325 kPa. The equilibrium data were measured in a recirculation still. The thermodynamic consistency of the data was checked and the composition dependence of the activity coefficients was fitted to the Wilson, the Redlich-Kister and the Abbott-Van Ness equations which all predict a non-existent azeotrope for this extraordinary system with the relative volatilities at 1.08 at most and strongly nonideal behavior. A specific maximum temperature azeotrope was found for this system with positive deviations from Raoult's law for the first two equations while the Abbott-Van Ness equation predicted a minimum temperature azeotrope. The excess molar volumes were calculated from densities determined pycnometrically and fitted to the Redlich-Kister polynomial." @default.
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- W2063953793 date "1993-08-01" @default.
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- W2063953793 title "Vapor—liquid equilibrium in the binary system ethanoic acid(1)—4-methyl-2-pentanone(2)" @default.
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- W2063953793 doi "https://doi.org/10.1016/0378-3812(93)85037-m" @default.
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