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- W2063956857 abstract "In order to clarify the polymerization process of molybdate, thermometric titrations were attempted for neutral sodium molybdate solution with mineral acids (hydrochloric acid and perchloric acid) and for acidified sodium molybdate solution with sodium hydroxide. From the inflections of the titration curve, the polymerization reaction was found to proceed from monomeric molybdate to heptamolybdate ion without any intermediate steps and this polyanion was then protonated to H2Mo7O244− followed by the formation of octamolybdate ion, when the initial concentration of the monomeric molybdate was high. On the other hand, with a low initial concentration the reaction proceeded directly to the octamolybdate. When a large amount of a neutral salt was present in the solution the first formed product was always heptamolybdate at any initial concentration of monomeric molybdate. The process, MoO42− → MoO246− → H2Mo7O244− → HMo8O263− → H4Mo8O26, is proposed. The heats of the polymerization reaction were measured for each step." @default.
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- W2063956857 date "1974-04-01" @default.
- W2063956857 modified "2023-10-14" @default.
- W2063956857 title "Thermometric titration in the investigation of the formation of polyanions of molybdenum(VI), tungsten(VI), vanadium(V), and chromium(VI)—II" @default.
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- W2063956857 doi "https://doi.org/10.1016/0022-1902(74)80824-9" @default.
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