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- W2063992140 abstract "The interaction of Cu(II)GlyGly with four nucleosides has been studied by difference electronic absorption spectroscopy. The relative stability of binding of nucleosides to Cu(II)GlyGly is in the order: cytidine ρ adenosine ≊ guanosine ρ uridine. The EPR spectra of these copper complexes have also been recorded at room temperature and at liquid nitrogen temperature. Bonding parameters characterising the covalency from the EPR data have also been calculated and analysed. It is concluded that the decrease in A∥ of copper complexes with increasing covalency in the coordination plane is due to a binding through nitrogen of nucleoside in the equatorial plane of Cu(II)GlyGly. The decrease in α2 with small increase in β21 supports the existence of competitive mechanisms of the in-plane σ- and π-bondings." @default.
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- W2063992140 date "1983-01-01" @default.
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- W2063992140 title "EPR and electronic absorption studies of interaction of Cu(II)glycylglycine complexes with nucleosides" @default.
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- W2063992140 doi "https://doi.org/10.1016/s0020-1693(00)86481-6" @default.
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