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• W2064004274 abstract "Ru complexes with chiral diphosphines and amine-based ligands achieve high catalytic activity and enantioselectivity for the hydrogenation of ketones under neutral to slightly basic conditions. The chiral environment is controllable by changing the combination of these two ligands. A concerted six-membered transition state is proposed to be the origin of the high reactivity. The eta(6)-arene/TsDPEN-Ru and MsDPEN-Cp(*)Ir catalysts effect the asymmetric reaction under slightly acidic conditions. A variety of chiral secondary alcohols are obtained in high enantiomeric excess." @default.
• W2064004274 created "2016-06-24" @default.
• W2064004274 creator A5066419790 @default.
• W2064004274 date "2010-01-01" @default.
• W2064004274 modified "2023-10-18" @default.
• W2064004274 title "Asymmetric hydrogenation of ketones: Tactics to achieve high reactivity, enantioselectivity, and wide scope" @default.
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• W2064004274 doi "https://doi.org/10.2183/pjab.86.202" @default.
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