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- W2064031736 abstract "Abstract The effect of flourine-gas treatment on both structural and superconducting properties of series of compounds deriving from the La 2 CuO 4 -type structure has been investigated. In La 2 CuO 4 the incorporation of anionic species into the lattice is corroborated by weight uptake, elemental analysis, increase of c-parameter, and neutron diffraction refinement. The starting semiconducting oxide is transformed to a superconducting “oxyfluoride” below T c = 40 K. In La 2−x−y RE x Sr y CuO 4 (RE = Nd, Gd) systems, the influence of the of the substituting RE has also been investigated. For instance in La 1.85−x Nd x Sr 0.15 CuO 4 , the whole range of compositions of the La 2 CuO 4 -type solid solution (0⩽x⩽1) becomes superconducting after fluorination. The occurrence of superconducting behavior has been ascribed to the increase of the formal oxidation state of copper due to the intercalation of anionic species." @default.
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- W2064031736 date "1991-12-01" @default.
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- W2064031736 title "Stabilization of new superconducting phases by low temperature flourination of La2CuO4-derived oxides" @default.
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- W2064031736 doi "https://doi.org/10.1016/0921-4534(91)92094-r" @default.
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