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- W2064075501 abstract "Selected members of the Pd–Te–Bi system (PdTe, PdTeBi and PdBi) have been synthesized from their constituent elements, their structure and phase integrity confirmed by x-ray diffraction and optical microscopy and their initial oxidation in air under ambient conditions investigated by means of XPS. Prior to air exposure, the Pd core-electron binding energies were 0.6–1.0 eV higher than the corresponding values for the pure metal, while the core-level shifts for the alloying elements were very small. In each case, oxidation was quite rapid, but the palladium did not appear to be directly involved in the initial reaction; no change in the Pd 3d spectrum other than in its intensity was observed, notwithstanding the formation of significant amounts of tellurium oxide and/or bismuth oxide. The electron spectra were consistent with an incongruent oxidation reaction leading to the formation of a layer of tellurium and/or bismuth oxide covering a palladium-enriched substrate." @default.
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- W2064075501 date "1996-09-16" @default.
- W2064075501 modified "2023-10-06" @default.
- W2064075501 title "XPS Evidence for the Incongruent Surface Oxidation of Minerals in the Pd-Te-BiSystem" @default.
- W2064075501 doi "https://doi.org/10.1002/(sici)1096-9918(19960916)24:9<641::aid-sia150>3.0.co;2-w" @default.
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