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• W2064089240 abstract "The physicochemical properties of the α,ω-type surfactant (disodium dodecyl disulfate) in aqueous solution have been investigated by means of surface tension, conductivity, solubilization of various solubilizates, static light scattering, and13C NMR chemical shifts. The surface tension and conductivity measurements indicate the existence of two discontinuities which are referred to as the first CMC and the second CMC. The α,ω-type surfactant molecules change their conformation at an air-water interface and form a “wicket-like” conformation at the second CMC. By the static light scattering being measured the micellar aggregation number above the second CMC is determined to be 90 ± 5 (25°C). This value agrees fairly well with that obtained by13C NMR chemical shift data. The above results support the notion that between the first CMC and the second CMC the α,ω-type surfactant forms premicellar (several numbers of aggregates) and, above the second CMC, forms ordinary micelles which are very loosely aggregated." @default.
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• W2064089240 date "1987-08-01" @default.
• W2064089240 modified "2023-10-16" @default.
• W2064089240 title "Physicochemical properties of the α,ω-type surfactant in aqueous solution" @default.
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• W2064089240 doi "https://doi.org/10.1016/0021-9797(87)90472-3" @default.
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