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• W2064110771 abstract "Dicarba analogues of the cyclic opioid peptides H-Tyr-c[d-Cys-Gly-Phe-d(or l)-Cys]NH2 were synthesized on solid phase by substituting allylglycines for the cysteines and cyclization by ring-closing metathesis between the side chains of the allylglycine residues. Mixtures of cis and trans isomers of the resulting olefinic peptides were obtained, and catalytic hydrogenation yielded the saturated −CH2−CH2− bridged peptides. The dicarba analogues retained high μ and δ agonist potencies. Remarkably, the trans isomer of H-Tyr-c[d-Allylgly-Gly-Phe-l-Allylgly]NH2 was a μ agonist/δ agonist with subnanomolar potency at both receptors." @default.
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• W2064110771 date "2007-02-22" @default.
• W2064110771 modified "2023-10-15" @default.
• W2064110771 title "Dicarba Analogues of the Cyclic Enkephalin Peptides H-Tyr-<i>c</i>[<scp>d</scp>-Cys-Gly-Phe-<scp>d</scp>(or <scp>l</scp>)-Cys]NH₂ Retain High Opioid Activity" @default.
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• W2064110771 doi "https://doi.org/10.1021/jm061294n" @default.
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