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- W2064119697 abstract "To determine the sorption rates of hydrogen in LaNi5 a set-up was designed that allowed the measurement of both the absorption and desorption rate in the two phase region. A charge chamber was charged (evacuated) with a small amount of hydrogen; a valve was opened to the sample; hydrogen was absorbed (given off) until the plateau pressure was reached. The resulting pressure changes could be fitted to a straight line by plotting the reciprocal pressure versus time. The measured sorption rates are independent of pressure (up to 5 atm) and independent of the sense of sorption (ab- or desorption). The sorption rates measured range from 15 s at 0 °C to 1 s at 90 °C until 2/3 of the admitted hydrogen is absorbed. If the sorption rates are plotted logarithmically versus 1/T, the activation energy for sorption can be determined as 7.6 kcal/mol H2. This value agrees closely with the formation energy of the LaNi5 hydride and thus leads to the conclusion that the phase transformation is the rate controlling process for sorption." @default.
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- W2064119697 title "Hydrogen sorption in LaNi5" @default.
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- W2064119697 doi "https://doi.org/10.1016/0022-5088(76)90182-x" @default.
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