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• W2064136174 abstract "The results of a spectroscopic and thermal study of high molecular weight (PEO)nNH4SO3CF3 (n = 1–80) complexes are presented. Infrared spectroscopy shows a shift and splitting of the NH stretching mode at high salt concentrations, indicating the interaction of NH4+ ions with the ether oxygen atoms of the polymer backbone. Combined spectroscopic and differential scanning calorimetric (DSC) studies confirm previously reported compound formation at ether oxygen:cation ratios of 8:1 and 4:1. These studies also indicate the formation of a 1:1 compound. The ionic conductivity of the 1:1 compound shows unusual temperature-dependent behavior, suggestive of a λ-transition." @default.
• W2064136174 created "2016-06-24" @default.
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• W2064136174 date "1996-11-02" @default.
• W2064136174 modified "2023-10-09" @default.
• W2064136174 title "Characterization studies on high molecular weight PEO-ammonium triflate complexes" @default.
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• W2064136174 doi "https://doi.org/10.1016/s0167-2738(96)00473-0" @default.
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