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- W2064138466 abstract "Rare kinks (1.74 × 10-3 kinks nm-1) on the otherwise molecularly straight 001 growth steps on the (010) face of orthorhombic lysozyme were studied. These straight steps are generated at the edge between the (010) and (110) faces. Each step is assumed to propagate by creation of one-dimensional (1D) `nuclei' - the segments of a new molecular rows irreversibly attached to the straight step in the course of a trial and error process. Each `nucleus' is built of two neighbouring unit cells and is thus limited by two kinks possessing opposite signs. The steps move along the face at a rate ~0.19 nm s-1, at relative supersaturation about unity. Kink statistics and step rate measurements allowed us to evaluate the velocity of the kink along the step to be 19.3 nm s-1, and corresponding average frequencies at which attachment to and detachment from a kink occur to be 50 and 25 molecules s-1, respectively. The rate at which the 1D `nuclei' appear at a step was found experimentally to be J = 2.7 × 10-5 nm-1 s-1." @default.
- W2064138466 created "2016-06-24" @default.
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- W2064138466 date "1999-11-25" @default.
- W2064138466 modified "2023-09-23" @default.
- W2064138466 title "Kink kinetics, exchange fluxes, 1D `nucleation' and adsorption on the (010) face of orthorhombic lysozyme crystals" @default.
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- W2064138466 doi "https://doi.org/10.1088/0953-8984/11/49/314" @default.
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