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• W2064151952 startingPage "214" @default.
• W2064151952 abstract "Polycrystalline ceramic samples of magnesia doped GdSm1–xMgxZr2O7–x/2 have been prepared by conventional solid state reaction method using high purity oxides. The influence of magnesia dopant content on densification, microstructure and electrical properties of GdSm1–xMgxZr2O7–x/2 ceramics are investigated. Magnesia doping promotes the sintering densification behaviour of GdSm1–xMgxZr2O7–x/2 ceramics. GdSm1–xMgxZr2O7–x/2 (x = 0, 0·05, 0·10) ceramics have a single phase of the pyrochlore type structure, while GdSm1–xMgxZr2O7–x/2 (x = 0·15, 0·20) ceramics consist of the pyrochlore type structure and a small amount of magnesia as the second phase. The total conductivity of GdSm1–xMgxZr2O7–x/2 ceramics obeys the Arrhenius relation, and gradually increases with increasing temperature from 723 to 1173 K. GdSm1–xMgxZr2O7–x/2 ceramics are oxide-ion conductors in the oxygen partial pressure range of 1·0×10–4 to 1·0 atm at each test temperature. The maximum value of the total conductivity is 1·29×10–2 S cm–1 at 1173 K for the GdSm0·85Mg0·15Zr2O6·925 ceramic." @default.
• W2064151952 created "2016-06-24" @default.
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• W2064151952 date "2012-05-01" @default.
• W2064151952 modified "2023-10-14" @default.
• W2064151952 title "Influence of magnesia doping on structure and electrical conductivity of pyrochlore type GdSmZr₂O₇" @default.
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• W2064151952 doi "https://doi.org/10.1179/1743676111y.0000000077" @default.
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