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- W2064195655 abstract "Abstract Two methods for the oxidative rearrangement of tertiary allylic alcohols have been developed. Most of tertiary allylic alcohols studied were oxidized to their corresponding transposed carbonyl derivatives in excellent to fair yields by reaction with TEMPO in combination with PhIO and Bi(OTf)3 or copper (II) chloride in the presence or not of oxygen. Other primary oxidants of TEMPO such as PhI(OAc)2, mCPBA, and Oxone® were unsatisfactory giving the enone in modest to low yields." @default.
- W2064195655 created "2016-06-24" @default.
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- W2064195655 date "2010-06-01" @default.
- W2064195655 modified "2023-09-25" @default.
- W2064195655 title "ChemInform Abstract: Lewis Acid-Catalyzed Oxidative Rearrangement of Tertiary Allylic Alcohols Mediated by TEMPO." @default.
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- W2064195655 doi "https://doi.org/10.1002/chin.201022033" @default.
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