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• W2064221444 abstract "Die Reaktion von [GaBi3]2− mit [Sm(C5Me4H)3] führte zur Bildung des ersten protonierten ternären intermetalloiden Clusters [Sm@Ga3−xH3−2xBi10+x]3− (1; x=0,1). Die Existenz von Ga-H-Bindungen und der Transfer von Elektronen und Protonen während der Bildung von 1 wurde durch Kombination verschiedener experimenteller und quantenchemischer Methoden beleuchtet, was auch die Rolle des Lösungsmittels 1,2-Diaminoethan als Brønsted-Säure unterstrich. Als organisches Nebenprodukt wurde das bisher nicht bekannte Octamethylfulven (2) erhalten, das durch eine C-C-Kupplung aus (C5Me4H)− hervorging." @default.
• W2064221444 created "2016-06-24" @default.
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• W2064221444 date "2014-09-11" @default.
• W2064221444 modified "2023-10-18" @default.
• W2064221444 title "Herkunft und Verbleib von Elektronen und Protonen bei der Bildung des intermetalloiden Clusters [Sm@Ga_3−<i>x</i>H_{3−2<i>x</i>}Bi_10+<i>x</i>]³⁻(<i>x</i>=0, 1)" @default.
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• W2064221444 doi "https://doi.org/10.1002/ange.201407288" @default.
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