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• W2064227037 abstract "A complete assignment of the IR spectra of the ionic and neutral hydrogen-bonded species formed by interaction of a series of bases of increasing proton affinity [methanol, ethanol, dimethyl ether, diethyl ether and tetrahydrofuran (THF)] with H-Y, H-ZSM-5, H-mordenite (H-Mord) and H-Nafion is given. Special attention is devoted to the discussion of spectral manifestations associated with structures varying with continuity from the true neutral AH⋯B form (low B proton affinity) to the true ionic A–⋯HB+ forms (high B proton affinity) passing through intermediate situations characterized by proton potentials with a single broad minimum or two minima separated by a low barrier (hesitating proton) and substantial ionic character. The assignment is based more on the comparison of the whole series of spectra than on the minute analysis of the specific properties of each spectrum. The assignment is also based on the comparison of the spectra of the adducts in zeolites with the spectra of analogous species formed in homogeneous conditions between acids and bases of comparable base and acid strengths (used as models)." @default.
• W2064227037 created "2016-06-24" @default.
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• W2064227037 date "1996-01-01" @default.
• W2064227037 modified "2023-10-17" @default.
• W2064227037 title "IR spectroscopy of neutral and ionic hydrogen-bonded complexes formed upon interaction of CH₃OH, C₂H₅OH, (CH₃)₂O, (C₂H₅)₂O and C₄H₈O with H-Y, H-ZSM-5 and H-mordenite: comparison with analogous adducts formed on the H-Nafion superacidic membrane" @default.
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• W2064227037 doi "https://doi.org/10.1039/ft9969204863" @default.
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