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- W2064258617 abstract "Amorphous Si-B-C-N alloys were deposited by reactive magnetron sputtering, and their high-temperature stability was investigated using a combined approach of experiment and molecular-dynamics simulations. We show that both a higher Si/C ratio and the addition of boron improve the thermal stability of the materials. We find that lifetimes of bonds of the same type are significantly longer at the higher Si/C ratio. The addition of boron results in a conversion of some of the electrons in lone pairs associated with nitrogen to bonding electrons. This increases the network's average coordination number. In both cases, the higher network coordination number and resulting lower diffusion, expressed in terms of longer bond lifetimes, shift decomposition reactions in materials to higher temperatures." @default.
- W2064258617 created "2016-06-24" @default.
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- W2064258617 date "2006-11-01" @default.
- W2064258617 modified "2023-09-29" @default.
- W2064258617 title "Effect of B and the Si/C ratio on high-temperature stability of Si–B–C–N materials" @default.
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- W2064258617 doi "https://doi.org/10.1209/epl/i2006-10283-5" @default.
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