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• W2064286305 abstract "Abstract Conjugate additions of cyclam to perfluorohexyl vinyl sulfone and sulfoxide, which act as efficient fluorous Michael acceptors, readily give access to new fluoro‐ponytail tetraazamacrocycles in good yields. The solubility of the N ‐tetrasubstituted macrocycles depends dramatically on the nature of the polar function (SO or SO 2 ): the sulfoxide cyclam derivative is soluble in perfluorodecaline (pfd) and perfluoromethylcyclohexane (pfmc) while the sulfonyl derivative is almost insoluble in organic or fluorous solvents. In agreement with the well known affinity of cyclam for copper(II) ions, stable copper complexes of the fluorous macrocyclic ligands have been isolated and characterized. In chloroform/methanol, complexes with four perfluorinated tails have been obtained from reaction of the tetra‐ N ‐perfluorohexylsulfinyl‐substituted macrocycle with copper nitrate and copper perfluorocarboxylate. In trifluoroethanol, a selective retro‐Michael reaction has been observed and the same reaction specifically gives copper complexes of the tri‐ N ‐substituted macrocycle. Complexes with three and four fluorous tails associated with perfluorocarboxylate counteranions are soluble in fluorous solvents (pfd and pfmc). These copper complexes were tested as catalysts for the oxidation of cyclohexene by molecular oxygen in the presence of tert ‐butyl hydroperoxide (tbhp). The oxidation reactions proceed under fluorous biphasic conditions and the catalyst can be recovered and reused. Quenching experiments indicate that cyclohexenyl hydroperoxide is the main oxidation product of the reaction performed with or without tbhp. Interestingly, these perfluorinated copper complexes are good, recyclable catalysts for the oxidation of cyclohexene by molecular oxygen without tbhp at room temperature and 65 °C.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)" @default.
• W2064286305 created "2016-06-24" @default.
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• W2064286305 date "2006-09-20" @default.
• W2064286305 modified "2023-10-03" @default.
• W2064286305 title "An Expedient Synthesis of Perfluorinated Tetraazamacrocycles: New Ligands for Copper‐Catalyzed Oxidation under Fluorous Biphasic Conditions" @default.
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• W2064286305 doi "https://doi.org/10.1002/ejoc.200600523" @default.
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