Matches in SemOpenAlex for { <https://semopenalex.org/work/W2064321484> ?p ?o ?g. }
Showing items 1 to 84 of
84
with 100 items per page.
- W2064321484 endingPage "2374" @default.
- W2064321484 startingPage "2369" @default.
- W2064321484 abstract "The reaction of RuCl3 with 4 molar equivalents of Na[Co(CO)4] gives a mixed cluster Na[RuCo3(CO)12] in high yield. The cluster readily undergoes a cation exchange by bulky cations such as [(Ph3P)2N]+, while protonolysis by phosphoric acid produces HRuCo3(CO)12. The X-ray structure of [(Ph3P)2N][RuCo3(CO)12] shows that the four metals are located at the corners of a tetrahedron. These mixed clusters are very effective for the homologation of methanol compared with Co2(CO)8. On the other hand, the Co2 (CO)8Ru3(CO)12 bimetallic catalyst shows remarkably high catalytic activity for hydroformylation of olefins such as cyclohexene compared with Co2(CO)8 alone. The synergistic effects for cobalt and ruthenium on these carbonylation reactions dre discussed. Metalloselective substitution reactions were observed when HRuCo3(CO)12 was treated with amines or phosphines. The substitution of amines for the carbonyl ligand takes place preferentially at the ruthenium atom whereas the substitution of phosphines occurs exclusively at the cobalt atoms." @default.
- W2064321484 created "2016-06-24" @default.
- W2064321484 creator A5044407607 @default.
- W2064321484 creator A5076833319 @default.
- W2064321484 date "1988-01-01" @default.
- W2064321484 modified "2023-10-09" @default.
- W2064321484 title "Chemistry of cobalt-ruthenium mixed metal complexes: Carbonylation and metalloselective substitution reactions" @default.
- W2064321484 cites W1835619336 @default.
- W2064321484 cites W1980883813 @default.
- W2064321484 cites W1993970941 @default.
- W2064321484 cites W2000624581 @default.
- W2064321484 cites W2005860119 @default.
- W2064321484 cites W2032654940 @default.
- W2064321484 cites W2035295655 @default.
- W2064321484 cites W2041227940 @default.
- W2064321484 cites W2057382827 @default.
- W2064321484 cites W2073833095 @default.
- W2064321484 cites W2312931162 @default.
- W2064321484 doi "https://doi.org/10.1016/s0277-5387(00)86354-8" @default.
- W2064321484 hasPublicationYear "1988" @default.
- W2064321484 type Work @default.
- W2064321484 sameAs 2064321484 @default.
- W2064321484 citedByCount "28" @default.
- W2064321484 countsByYear W20643214842013 @default.
- W2064321484 crossrefType "journal-article" @default.
- W2064321484 hasAuthorship W2064321484A5044407607 @default.
- W2064321484 hasAuthorship W2064321484A5076833319 @default.
- W2064321484 hasConcept C100805817 @default.
- W2064321484 hasConcept C111185830 @default.
- W2064321484 hasConcept C116569031 @default.
- W2064321484 hasConcept C155647269 @default.
- W2064321484 hasConcept C161790260 @default.
- W2064321484 hasConcept C168382676 @default.
- W2064321484 hasConcept C170493617 @default.
- W2064321484 hasConcept C178790620 @default.
- W2064321484 hasConcept C179104552 @default.
- W2064321484 hasConcept C185592680 @default.
- W2064321484 hasConcept C2779588249 @default.
- W2064321484 hasConcept C43411465 @default.
- W2064321484 hasConcept C512735826 @default.
- W2064321484 hasConcept C515602321 @default.
- W2064321484 hasConcept C521398313 @default.
- W2064321484 hasConcept C55493867 @default.
- W2064321484 hasConcept C555196967 @default.
- W2064321484 hasConcept C75473681 @default.
- W2064321484 hasConceptScore W2064321484C100805817 @default.
- W2064321484 hasConceptScore W2064321484C111185830 @default.
- W2064321484 hasConceptScore W2064321484C116569031 @default.
- W2064321484 hasConceptScore W2064321484C155647269 @default.
- W2064321484 hasConceptScore W2064321484C161790260 @default.
- W2064321484 hasConceptScore W2064321484C168382676 @default.
- W2064321484 hasConceptScore W2064321484C170493617 @default.
- W2064321484 hasConceptScore W2064321484C178790620 @default.
- W2064321484 hasConceptScore W2064321484C179104552 @default.
- W2064321484 hasConceptScore W2064321484C185592680 @default.
- W2064321484 hasConceptScore W2064321484C2779588249 @default.
- W2064321484 hasConceptScore W2064321484C43411465 @default.
- W2064321484 hasConceptScore W2064321484C512735826 @default.
- W2064321484 hasConceptScore W2064321484C515602321 @default.
- W2064321484 hasConceptScore W2064321484C521398313 @default.
- W2064321484 hasConceptScore W2064321484C55493867 @default.
- W2064321484 hasConceptScore W2064321484C555196967 @default.
- W2064321484 hasConceptScore W2064321484C75473681 @default.
- W2064321484 hasIssue "22-23" @default.
- W2064321484 hasLocation W20643214841 @default.
- W2064321484 hasOpenAccess W2064321484 @default.
- W2064321484 hasPrimaryLocation W20643214841 @default.
- W2064321484 hasRelatedWork W2034735037 @default.
- W2064321484 hasRelatedWork W2068085831 @default.
- W2064321484 hasRelatedWork W2070956392 @default.
- W2064321484 hasRelatedWork W2085242957 @default.
- W2064321484 hasRelatedWork W2119065826 @default.
- W2064321484 hasRelatedWork W2344683157 @default.
- W2064321484 hasRelatedWork W2949236439 @default.
- W2064321484 hasRelatedWork W2977702061 @default.
- W2064321484 hasRelatedWork W3155947632 @default.
- W2064321484 hasRelatedWork W4211242886 @default.
- W2064321484 hasVolume "7" @default.
- W2064321484 isParatext "false" @default.
- W2064321484 isRetracted "false" @default.
- W2064321484 magId "2064321484" @default.
- W2064321484 workType "article" @default.