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- W2064346772 abstract "The downstream near afterglow region of a hydrogen plasma is used to decompose and convert trimethylarsine (TMAs) into methylarsine homologs [(CH3)3−xAsHx, where x=1,2,3] including that of arsine (x=3). Approximately 30%, 17%, and 10% of the TMAs is converted into dimethylarsine (DMAs), monomethylarsine (MMAs), and arsine, respectively, while 28% remains undecomposed. Hydrogen is replaced by deuterium to isotopically verify that the origin of the arsenic hydrogenation occurring during gas conversion arises from both the plasma gas and fragmented hydrogen from the TMAs. Deuterium tagging of the MMAs, DMAs, and hydrocarbon byproducts is consistent with TMAs decomposition via plasma initiated CH3 radical removal and explains why the predominant light stable hydrocarbon produced is methane while ethane and acetylene account for the main higher hydrocarbons." @default.
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- W2064346772 date "1991-09-15" @default.
- W2064346772 modified "2023-09-26" @default.
- W2064346772 title "Plasma-assisted decomposition of trimethylarsine" @default.
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- W2064346772 doi "https://doi.org/10.1063/1.349266" @default.
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