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- W2064361901 abstract "To analyze the thermorheological behavior of various polyethylenes, the relaxation spectra were shifted. Not only linear and short-chain branched PE but also the classical high-pressure LDPE were found to be thermorheologically simple, i.e., the activation energy Ea is independent of the relaxation strength or the relaxation time, respectively. However, for the long-chain branched metallocene catalyzed polyethylenes investigated a significant dependence of the activation energy Ea on the relaxation time is detected. At shorter relaxation times Ea is very close to that of linear PE, but it increases with longer times. The lower Ea values are assumed to be due to linear molecules and the higher ones to different species of long-chain branched molecules. These findings offer the possibility to use the analysis of the thermorheological complexity to get an insight into the branching structure of polyethylenes. For the LCB−mPE investigated, it can be concluded that they are a mixture of linear and long-chain branched chains." @default.
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- W2064361901 date "2008-01-30" @default.
- W2064361901 modified "2023-09-27" @default.
- W2064361901 title "Thermorheological Behavior of Various Long-Chain Branched Polyethylenes" @default.
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- W2064361901 doi "https://doi.org/10.1021/ma702367a" @default.
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