FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2064419543> ?p ?o ?g. }

• W2064419543 endingPage "8385" @default.
• W2064419543 startingPage "8376" @default.
• W2064419543 abstract "The synthesis and photophysical studies of a fullerene [6:0]-hexaadduct that carries 12 pyropheophorbide a units are reported. The synthesis started with the malonate 1, which was coupled under template conditions to C(60)() to give the hexaadduct 2. After removal of the protecting group with acid the dodecakis amino-substituted precursor compound 3 was generated. 3 was not isolated but directly reacted with the N-succinimid ester 4 of pyropheophorbide a (5), which delivered the desired fullerene [6:0]-hexaadduct 6 in excellent yield. The photophysical properties of 6 were studied and compared with those of the fullerene [5:1]-hexaadduct 7 with six pyropheophorbide a groups and the bispyropheophorbide a-fullerene [5:1]-hexaadduct 8. The pyropheophorbide a units in 6 undergo after light absorption very efficient energy transfer as well as partly excitonic interaction. The last process results in formation of energy traps, which could be resolved experimentally. Compared to the reference compounds 7 and 8, 6 has a higher probability of trap formation due to a higher local concentration of dye molecules and shorter distances between them. As a consequence, the excitation energy is delivered rapidly (within 23 ps) to the traps, resulting in decreases of the fluorescence, intersystem crossing, and singlet oxygen quantum yields in comparison with the values of the reference compounds." @default.
• W2064419543 created "2016-06-24" @default.
• W2064419543 creator A5019368171 @default.
• W2064419543 creator A5035247254 @default.
• W2064419543 creator A5039595421 @default.
• W2064419543 creator A5041427493 @default.
• W2064419543 creator A5061810156 @default.
• W2064419543 creator A5062780612 @default.
• W2064419543 date "2005-05-20" @default.
• W2064419543 modified "2023-09-23" @default.
• W2064419543 title "Dissipation of Electronic Excitation Energy within a C₆₀ [6:0]-Hexaadduct Carrying 12 Pyropheophorbide <i>a</i> Moieties" @default.
• W2064419543 cites W1966888525 @default.
• W2064419543 cites W1974688247 @default.
• W2064419543 cites W1975297361 @default.
• W2064419543 cites W1980508098 @default.
• W2064419543 cites W1990341425 @default.
• W2064419543 cites W1997318959 @default.
• W2064419543 cites W2000776563 @default.
• W2064419543 cites W2008114749 @default.
• W2064419543 cites W2013543704 @default.
• W2064419543 cites W2023736957 @default.
• W2064419543 cites W2034078366 @default.
• W2064419543 cites W2037094678 @default.
• W2064419543 cites W2038607502 @default.
• W2064419543 cites W2047166416 @default.
• W2064419543 cites W2048313475 @default.
• W2064419543 cites W2051206787 @default.
• W2064419543 cites W2055513825 @default.
• W2064419543 cites W2056446665 @default.
• W2064419543 cites W2062082636 @default.
• W2064419543 cites W2063170329 @default.
• W2064419543 cites W2063978098 @default.
• W2064419543 cites W2070381607 @default.
• W2064419543 cites W2070469179 @default.
• W2064419543 cites W2070950463 @default.
• W2064419543 cites W2075134695 @default.
• W2064419543 cites W2081645293 @default.
• W2064419543 cites W2094346859 @default.
• W2064419543 cites W2101306131 @default.
• W2064419543 cites W2106757599 @default.
• W2064419543 cites W2119796129 @default.
• W2064419543 cites W2121274259 @default.
• W2064419543 cites W2139682729 @default.
• W2064419543 cites W2142455658 @default.
• W2064419543 cites W2160936791 @default.
• W2064419543 cites W2162997230 @default.
• W2064419543 cites W2164498071 @default.
• W2064419543 cites W2328366366 @default.
• W2064419543 cites W2482083625 @default.
• W2064419543 cites W2950849637 @default.
• W2064419543 cites W2952524736 @default.
• W2064419543 cites W2953139510 @default.
• W2064419543 doi "https://doi.org/10.1021/ja0503581" @default.
• W2064419543 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15941271" @default.
• W2064419543 hasPublicationYear "2005" @default.
• W2064419543 type Work @default.
• W2064419543 sameAs 2064419543 @default.
• W2064419543 citedByCount "31" @default.
• W2064419543 countsByYear W20644195432014 @default.
• W2064419543 countsByYear W20644195432015 @default.
• W2064419543 countsByYear W20644195432016 @default.
• W2064419543 countsByYear W20644195432017 @default.
• W2064419543 countsByYear W20644195432018 @default.
• W2064419543 countsByYear W20644195432019 @default.
• W2064419543 countsByYear W20644195432020 @default.
• W2064419543 countsByYear W20644195432023 @default.
• W2064419543 crossrefType "journal-article" @default.
• W2064419543 hasAuthorship W2064419543A5019368171 @default.
• W2064419543 hasAuthorship W2064419543A5035247254 @default.
• W2064419543 hasAuthorship W2064419543A5039595421 @default.
• W2064419543 hasAuthorship W2064419543A5041427493 @default.
• W2064419543 hasAuthorship W2064419543A5061810156 @default.
• W2064419543 hasAuthorship W2064419543A5062780612 @default.
• W2064419543 hasConcept C106447425 @default.
• W2064419543 hasConcept C119599485 @default.
• W2064419543 hasConcept C121332964 @default.
• W2064419543 hasConcept C125287762 @default.
• W2064419543 hasConcept C127413603 @default.
• W2064419543 hasConcept C134121241 @default.
• W2064419543 hasConcept C159467904 @default.
• W2064419543 hasConcept C162862793 @default.
• W2064419543 hasConcept C171001562 @default.
• W2064419543 hasConcept C178790620 @default.
• W2064419543 hasConcept C181500209 @default.
• W2064419543 hasConcept C184779094 @default.
• W2064419543 hasConcept C185592680 @default.
• W2064419543 hasConcept C191897082 @default.
• W2064419543 hasConcept C192562407 @default.
• W2064419543 hasConcept C24890656 @default.
• W2064419543 hasConcept C2777516457 @default.
• W2064419543 hasConcept C2777552763 @default.
• W2064419543 hasConcept C32909587 @default.
• W2064419543 hasConcept C33062035 @default.
• W2064419543 hasConcept C540031477 @default.
• W2064419543 hasConcept C62520636 @default.
• W2064419543 hasConcept C73978554 @default.
• W2064419543 hasConcept C75473681 @default.
• W2064419543 hasConcept C83581075 @default.

• next