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- W2064430171 abstract "Abstract The reaction of thiocyanate and hydrogen peroxide is catalyzed by lactoperoxidase (donor: H2O2 oxidoreductase, EC 1.11.1.7). The initial products are cyanide and sulfate ions. Cyanide rapidly disappears from the incubation mixture. The oxidation of cyanide by hydrogen peroxide is not catalyzed by lactoperoxidase at pH 5.7, but intermediary compounds produced in the course of the oxidation of thiocyanate react with cyanide. Cyanate, and presumably sulfur dicyanide, are formed. The latter is oxidized by the hydrogen peroxide-lactoperoxidase system to sulfate and cyanide; cyanate is spontaneously hydrolyzed to ammonia. The lactoperoxidase-catalyzed reaction of thiocyanate with hydrogen peroxide resembles the acid-catalyzed rather than the pH-independent reaction." @default.
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- W2064430171 date "1970-11-01" @default.
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- W2064430171 title "Oxidation of thiocyanate to cyanide and sulfate by the lactoperoxidase-hydrogen peroxide system" @default.
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- W2064430171 doi "https://doi.org/10.1016/0003-9861(70)90108-6" @default.
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