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• W2064484527 startingPage "1670" @default.
• W2064484527 abstract "Abstract We show that electron transfer from the perchlorotriphenylmethide anion (PTM − ) to Y@C 82 ( C 2 v ) is an instantaneous process, suggesting potential applications for using PTM − to perform redox titrations of numerous endohedral metallofullerenes. The first representative of a Y@C 82 ‐based salt containing the complex cation was prepared by treating Y@C 82 ( C 2 v ) with the [K + ([18]crown‐6)]PTM − salt. The synthesis developed involves the use of the [K + ([18]crown‐6)]PTM − salt as a provider of both a complex cation and an electron‐donating anion that is able to reduce Y@C 82 ( C 2 v ). For the first time, the molar absorption coefficients for neutral and anionic forms of the pure isomer of Y@C 82 ( C 2 v ) were determined in organic solvents with significantly different polarities." @default.
• W2064484527 created "2016-06-24" @default.
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• W2064484527 date "2013-03-28" @default.
• W2064484527 modified "2023-10-17" @default.
• W2064484527 title "Harnessing Electron Transfer from the Perchlorotriphenylmethide Anion to Y@C₈₂(<i>C</i>_2<i>v</i>) to Engineer an Endometallofullerene-Based Salt" @default.
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• W2064484527 doi "https://doi.org/10.1002/cphc.201300107" @default.
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