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• W2064519079 abstract "The effects of epoxidized natural rubber (ENR-50) as a compatibilizer on the properties of styrene butadiene rubber/recycled acrylonitrile-butadiene rubber (SBR/NBRr) blends were studied. Styrene butadiene rubber/recycled acrylonitrile-butadiene rubber (SBR/NBRr) blends were prepared by two-roll mill with five different compositions (i.e., 85/5/10, 75/15/10, 65/25/10, 55/35/10 and 40/50/10), with the ENR-50 content fixed at 10 phr. Cure characteristics, mechanical properties, FTIR analysis, differential scanning calorimetry (DSC) and morphology (SEM) studies were performed to determine the compatibility of SBR/NBRr blends in the presence of ENR-50. The cure characteristics showed that SBR/NBRr blends with the presence of ENR-50 have lower scorch time t2 and cure time t90 than SBR/NBRr blends without ENR-50. The SBR/NBRr blends with ENR-50 exhibited lower minimum torque (ML) compared with SBR/NBRr blends without ENR-50, which indicates better processability of the blends after compatibilization. However, SBR/NBRr blends with ENR-50 exhibited a higher value of maximum torque (MH) than SBR/NBRr blends without ENR-50. The incorporation of ENR-50 improved the tensile strength and tensile modulus (M100, stress at 100% elongation) of SBR/NBRr blends with ENR-50 compared with SBR/NBRr blends without ENR-50 at all blend ratios. Nevertheless, the addition of ENR-50 reduced the elongation at break (Eb) and rebound resilience of compatibilized SBR/NBRr blends compared with SBR/NBRr without ENR-50. The improvement in hardness upon compatibilization is due to an increase in crosslink density. FTIR analysis showed that ENR-50 is compatible with NBRr through the oxirane group and with SBR through the isoprene group. Differential scanning calorimetry results show an improvement in the compatibility of SBR/NBRr blends with the presence of ENR-50. Scanning electron microscopy (SEM) of the fracture surfaces indicates that, with the addition of ENR-50 in SBR/NBRr blends, better adhesion between SBR and NBRr was obtained, thus improving the compatibility of SBR/NBRr blends." @default.
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• W2064519079 date "2010-04-01" @default.
• W2064519079 modified "2023-10-16" @default.
• W2064519079 title "Characterization of styrene butadiene rubber/recycled acrylonitrile-butadiene rubber (SBR/NBRr) blends: The effects of epoxidized natural rubber (ENR-50) as a compatibilizer" @default.
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• W2064519079 doi "https://doi.org/10.1016/j.polymertesting.2009.11.002" @default.
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