Matches in SemOpenAlex for { <https://semopenalex.org/work/W2064535362> ?p ?o ?g. }
- W2064535362 endingPage "5867" @default.
- W2064535362 startingPage "5858" @default.
- W2064535362 abstract "Secondary particulate organic matter (POM) formed in a flow reactor by the OH-radical-induced reactions of toluene was collected on quartz fiber filters, and its stable carbon isotope ratio was analyzed by off-line combustion and subsequent dual-inlet isotope ratio mass spectrometry. The toluene consumption in these experiments ranged from 7% to 29%. The stable carbon isotope composition (δ13C) of the secondary POM was in the range of −32.2‰ to −32.9‰ (VPDB scale), with some indication for a slight dependence on the extent of toluene consumption. These measured δ13C values were, on average, 5.8‰ lighter than those of the parent toluene. Those observations are slightly lower than the δ13C values of the sum of all toluene oxidation products (from −31.6‰ to −32.3‰) that are predicted using the kinetic isotope effect for the reaction of toluene with OH-radical under these reaction conditions and the initial δ13C of the parent toluene. Therefore, mass balance dictates that the fractionation between gas-phase and particle-phase products is small. On average, the particle-phase products are 0.6‰±0.2‰ lighter than the gas-phase products. This is in agreement with the concept that the initial reaction of toluene with the OH-radical is the slowest step in the reaction sequence resulting in POM formation." @default.
- W2064535362 created "2016-06-24" @default.
- W2064535362 creator A5002680660 @default.
- W2064535362 creator A5003227470 @default.
- W2064535362 creator A5021079454 @default.
- W2064535362 creator A5021350494 @default.
- W2064535362 creator A5023619589 @default.
- W2064535362 creator A5011783014 @default.
- W2064535362 date "2006-09-01" @default.
- W2064535362 modified "2023-10-10" @default.
- W2064535362 title "Flow reactor studies of the stable carbon isotope composition of secondary particulate organic matter generated by OH-radical-induced reactions of toluene" @default.
- W2064535362 cites W1620282461 @default.
- W2064535362 cites W1973026421 @default.
- W2064535362 cites W1973255372 @default.
- W2064535362 cites W1980974838 @default.
- W2064535362 cites W1981143685 @default.
- W2064535362 cites W1985434973 @default.
- W2064535362 cites W1988591536 @default.
- W2064535362 cites W1989541832 @default.
- W2064535362 cites W1992092441 @default.
- W2064535362 cites W2000279082 @default.
- W2064535362 cites W2005686995 @default.
- W2064535362 cites W2008862278 @default.
- W2064535362 cites W2024051163 @default.
- W2064535362 cites W2040557596 @default.
- W2064535362 cites W2054694823 @default.
- W2064535362 cites W2056570381 @default.
- W2064535362 cites W2062540230 @default.
- W2064535362 cites W2067644827 @default.
- W2064535362 cites W2075668796 @default.
- W2064535362 cites W2081634757 @default.
- W2064535362 cites W2086421485 @default.
- W2064535362 cites W2091639554 @default.
- W2064535362 cites W2096906074 @default.
- W2064535362 cites W2116985822 @default.
- W2064535362 cites W2119744638 @default.
- W2064535362 cites W2168923039 @default.
- W2064535362 doi "https://doi.org/10.1016/j.atmosenv.2006.05.001" @default.
- W2064535362 hasPublicationYear "2006" @default.
- W2064535362 type Work @default.
- W2064535362 sameAs 2064535362 @default.
- W2064535362 citedByCount "72" @default.
- W2064535362 countsByYear W20645353622012 @default.
- W2064535362 countsByYear W20645353622013 @default.
- W2064535362 countsByYear W20645353622014 @default.
- W2064535362 countsByYear W20645353622015 @default.
- W2064535362 countsByYear W20645353622016 @default.
- W2064535362 countsByYear W20645353622017 @default.
- W2064535362 countsByYear W20645353622018 @default.
- W2064535362 countsByYear W20645353622019 @default.
- W2064535362 countsByYear W20645353622020 @default.
- W2064535362 countsByYear W20645353622021 @default.
- W2064535362 countsByYear W20645353622022 @default.
- W2064535362 countsByYear W20645353622023 @default.
- W2064535362 crossrefType "journal-article" @default.
- W2064535362 hasAuthorship W2064535362A5002680660 @default.
- W2064535362 hasAuthorship W2064535362A5003227470 @default.
- W2064535362 hasAuthorship W2064535362A5011783014 @default.
- W2064535362 hasAuthorship W2064535362A5021079454 @default.
- W2064535362 hasAuthorship W2064535362A5021350494 @default.
- W2064535362 hasAuthorship W2064535362A5023619589 @default.
- W2064535362 hasBestOaLocation W20645353622 @default.
- W2064535362 hasConcept C105923489 @default.
- W2064535362 hasConcept C113196181 @default.
- W2064535362 hasConcept C158787203 @default.
- W2064535362 hasConcept C178790620 @default.
- W2064535362 hasConcept C185059815 @default.
- W2064535362 hasConcept C185592680 @default.
- W2064535362 hasConcept C2778142098 @default.
- W2064535362 hasConcept C2779334269 @default.
- W2064535362 hasConcept C97428945 @default.
- W2064535362 hasConceptScore W2064535362C105923489 @default.
- W2064535362 hasConceptScore W2064535362C113196181 @default.
- W2064535362 hasConceptScore W2064535362C158787203 @default.
- W2064535362 hasConceptScore W2064535362C178790620 @default.
- W2064535362 hasConceptScore W2064535362C185059815 @default.
- W2064535362 hasConceptScore W2064535362C185592680 @default.
- W2064535362 hasConceptScore W2064535362C2778142098 @default.
- W2064535362 hasConceptScore W2064535362C2779334269 @default.
- W2064535362 hasConceptScore W2064535362C97428945 @default.
- W2064535362 hasIssue "30" @default.
- W2064535362 hasLocation W20645353621 @default.
- W2064535362 hasLocation W20645353622 @default.
- W2064535362 hasLocation W20645353623 @default.
- W2064535362 hasLocation W20645353624 @default.
- W2064535362 hasOpenAccess W2064535362 @default.
- W2064535362 hasPrimaryLocation W20645353621 @default.
- W2064535362 hasRelatedWork W1967564482 @default.
- W2064535362 hasRelatedWork W2014584709 @default.
- W2064535362 hasRelatedWork W2077736396 @default.
- W2064535362 hasRelatedWork W2417927149 @default.
- W2064535362 hasRelatedWork W2592895429 @default.
- W2064535362 hasRelatedWork W2892830114 @default.
- W2064535362 hasRelatedWork W2895600093 @default.
- W2064535362 hasRelatedWork W3128255749 @default.
- W2064535362 hasRelatedWork W4236010733 @default.
- W2064535362 hasRelatedWork W4247276742 @default.
- W2064535362 hasVolume "40" @default.