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• W2064540273 abstract "Container-shaped molecules provide structured environments that impart geometric bounds on the motions and conformations of smaller molecular occupants. Moreover, they provide solvation that is constrained in time and space. When inwardly directed functional groups are present, they can interact chemically with the occupants. Additionally, the potential for reactivity and catalysis is greatly enhanced. Deep cavitands, derived from resorcinarenes, nearly surround smaller molecules and have been one of the most successful platforms for elaboration with functional groups. Derivatives bearing organic and metal-binding functional groups have been shown to affect recognition properties and selectively accelerate diverse reactions. In this review, we examine recent examples of these systems with an emphasis on how and why ordered nanoenvironments impart changes in the properties and reactivity of their occupants." @default.
• W2064540273 created "2016-06-24" @default.
• W2064540273 creator A5049521891 @default.
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• W2064540273 date "2005-07-25" @default.
• W2064540273 modified "2023-10-11" @default.
• W2064540273 title "Functional cavitands: Chemical reactivity in structured environments" @default.
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• W2064540273 doi "https://doi.org/10.1073/pnas.0501731102" @default.
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