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- W2064541569 abstract "Titration calorimetry was applied for the study of “inverted” micelles formed by α-glycerylmonooleate (GMO) in decalin. The enthalpy of micelle formation was found to be 10.16 kcal per monomer unit. Results of calorimetric titrations were used to calculate the fraction of the micelles in solution as a function of the overall concentration of the detergent. The observed sharp deflections in the titration curves indicate that the CMC concept may be useful for the description of the behavior of such systems. It is suggested that the concept of operational CMC should be applied whenever a major equilibrium governs the formation of the micelles within a narrow concentration range. Thus defined CMC represents aggregation of 50% of the detergent into “inverted” micelles. The results for pure GMO in decalin can be represented by a single equilibrium with K = 2.8 × 1018M−8. They yield n = 9 as aggregation number of GMO-P and 5 × 10−3M as its CMC. Approximately 75% of the micelles are formed within the concentration range of 3 × 10−3 × 10−2M. Impurities affect strongly the size, the nature, and the thermodynamic parameters of the GMO micelles in decalin." @default.
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- W2064541569 date "1985-05-01" @default.
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- W2064541569 title "Inverted micelles of monoolein in decalin: Calorimetric determination of equilibriuim constants and degrees of association" @default.
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- W2064541569 doi "https://doi.org/10.1016/0021-9797(85)90348-0" @default.
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