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- W2064554511 abstract "Abstract The density profile of a polar fluid near an uncharged wall decays as A/z 3 when the distance z to the wall becomes very large, this behavior is due to the existence of image forces. Similarly, the potential of mean force between the wall and a single ion in this solvent decays as B/z. The coefficients A and B can be calculated exactly by diagrammatic methods and compared to the predictions of macroscopic electrostatics. The values of A and B obtained by the hypernetted - chain (HNC) approximation differ strongly from the exact ones." @default.
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- W2064554511 date "1991-07-01" @default.
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- W2064554511 title "The distribution of polar molecules and ions near a solid surface. The asymptotic behavior of the profile as a test of the HNC approximation." @default.
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- W2064554511 doi "https://doi.org/10.1016/0167-7322(91)80004-n" @default.
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