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- W2064570775 abstract "The mechanism of hydrocarbon oxidation has been surveyed, with particular reference to the lower hydrocarbons. The initiation process has been briefly discussed to emphasize that homogeneous initiation is likely to be masked, certainly below 500°C, either by surface initiation or by secondary initiation caused by a reactive intermediate. The equilibrium R+O 2 ⇌ RO 2 plays a major part in deciding the reaction path and determines whether the main oxidation products are formed directly from R, or via RO 2 . Evidence to show the importance of this equilibriu, event at temperatures as high as 500°C, is presented, and at these temperatures radical pyrolysis may become important. Radical-radical reactions have frequently been introduced as termination steps, but situations where propagation reactions may occur are discussed." @default.
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- W2064570775 date "1973-01-01" @default.
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- W2064570775 title "Problems and progress in hydrocarbon oxidation" @default.
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- W2064570775 doi "https://doi.org/10.1016/s0082-0784(73)80025-6" @default.
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