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- W2064571612 abstract "The new 1,1′-binaphthylazepine ligand 1c has been prepared and tested in the enantioselective addition of Et2Zn to arylaldehydes, allowing us to reach ee’s up to 97% and giving extremely rapid reactions (10–20 min). Aminoalcohol 1c and the analogous compounds 1a and 1b were then tested in the enantioselective addition of Bu2Zn and Me2Zn to arylaldehydes. All of the ligands efficiently catalyze the Bu2Zn addition to benzaldehyde, providing good yields in short reaction times (2–4 h) and high ee (up to 96%). In the enantioselective methylation of arylaldehydes ligands 1b and 1c gave high yields (88–97%) and good to high (80–90%) ee’s." @default.
- W2064571612 created "2016-06-24" @default.
- W2064571612 creator A5046185021 @default.
- W2064571612 creator A5070848652 @default.
- W2064571612 date "2008-08-01" @default.
- W2064571612 modified "2023-10-14" @default.
- W2064571612 title "1,1′-Binaphthylazepine-based ligands for the enantioselective dialkylzinc addition to aromatic aldehydes" @default.
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- W2064571612 doi "https://doi.org/10.1016/j.tetasy.2008.07.026" @default.
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