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• W2064585816 abstract "Abstract Optical absorption spectra of trapped electrons produced by pulse radiolysis in glassy matrices of pure ethylene glycol (EG) and 1,3-propane diol (PD) were examined at 6, 90 and 150 K in the visible range. The end-of-pulse values of λmax for EG are 600, 550 and 530 nm at 6, 90 and 150 K respectively, whereas for PD the corresponding maxima are found at 620, 580 and 550 nm. Initial absorbances at maxima do not change with temperature in EG and PD except at 150 K when in PD the absorbance increases The maximum of absorption for both diols shifts towards blue with increasing temperature and time. This effect is more prominent in PD as compared to EG. The observed behaviour can be attributed to the molecular structures of the two matrices." @default.
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• W2064585816 date "1990-01-01" @default.
• W2064585816 modified "2023-09-26" @default.
• W2064585816 title "Pulse radiolysis of ethylene glycol and 1,3-propanediol glasses—I. Absorption spectra of trapped electrons" @default.
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• W2064585816 doi "https://doi.org/10.1016/1359-0197(90)90170-m" @default.
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