Matches in SemOpenAlex for { <https://semopenalex.org/work/W2064661036> ?p ?o ?g. }
- W2064661036 endingPage "1433" @default.
- W2064661036 startingPage "1430" @default.
- W2064661036 abstract "The solid-state structure of unsolvated, Lewis base-free phenyllithium (LiC6H5) is reported. Structure determination of the simplest lithium aryl was performed by high-resolution synchrotron X-ray powder diffraction. The structure was solved by ab initio methods in combination with difference Fourier analysis and consecutive Rietveld refinements. Solid phenyllithium consists of dimeric Li2Ph2 molecules, which strongly interact with adjacent Li2Ph2 moieties, forming a polymeric, infinite-ladder structure along the crystallographic b-axis. In the Li2Ph2 units the two lithium atoms and the C(ipso) atoms of the two phenyl rings form an absolutely planar, four-membered ring with the two phenyl rings perpendicular to it. The bonding of the C(ipso) atom to the two Li atoms can be described as a three-center, two-electron bond (Li−C 2.24(1) and 2.32(1) Å; Li−C−Li‘ 63.2(7)°). The π-electrons of the phenyl rings interact strongly with the lithium atoms of neighboring Li2Ph2 moieties." @default.
- W2064661036 created "2016-06-24" @default.
- W2064661036 creator A5013128882 @default.
- W2064661036 creator A5070746137 @default.
- W2064661036 creator A5079811691 @default.
- W2064661036 date "1998-02-01" @default.
- W2064661036 modified "2023-10-10" @default.
- W2064661036 title "Lewis Base-Free Phenyllithium: Determination of the Solid-State Structure by Synchrotron Powder Diffraction" @default.
- W2064661036 cites W1977935474 @default.
- W2064661036 cites W2006002048 @default.
- W2064661036 cites W2045990695 @default.
- W2064661036 cites W2048226783 @default.
- W2064661036 cites W2049251869 @default.
- W2064661036 cites W2050485263 @default.
- W2064661036 cites W2050991508 @default.
- W2064661036 cites W2052584975 @default.
- W2064661036 cites W2058683842 @default.
- W2064661036 cites W2067290420 @default.
- W2064661036 cites W2074916833 @default.
- W2064661036 cites W2083115119 @default.
- W2064661036 cites W2087837675 @default.
- W2064661036 cites W2099592176 @default.
- W2064661036 cites W2109286706 @default.
- W2064661036 cites W2151736521 @default.
- W2064661036 cites W2159081899 @default.
- W2064661036 cites W2584512756 @default.
- W2064661036 cites W2949374789 @default.
- W2064661036 cites W2950107398 @default.
- W2064661036 cites W942313901 @default.
- W2064661036 doi "https://doi.org/10.1021/ja972816e" @default.
- W2064661036 hasPublicationYear "1998" @default.
- W2064661036 type Work @default.
- W2064661036 sameAs 2064661036 @default.
- W2064661036 citedByCount "77" @default.
- W2064661036 countsByYear W20646610362012 @default.
- W2064661036 countsByYear W20646610362013 @default.
- W2064661036 countsByYear W20646610362014 @default.
- W2064661036 countsByYear W20646610362015 @default.
- W2064661036 countsByYear W20646610362016 @default.
- W2064661036 countsByYear W20646610362018 @default.
- W2064661036 countsByYear W20646610362019 @default.
- W2064661036 countsByYear W20646610362020 @default.
- W2064661036 countsByYear W20646610362021 @default.
- W2064661036 countsByYear W20646610362022 @default.
- W2064661036 crossrefType "journal-article" @default.
- W2064661036 hasAuthorship W2064661036A5013128882 @default.
- W2064661036 hasAuthorship W2064661036A5070746137 @default.
- W2064661036 hasAuthorship W2064661036A5079811691 @default.
- W2064661036 hasConcept C115624301 @default.
- W2064661036 hasConcept C115645028 @default.
- W2064661036 hasConcept C120665830 @default.
- W2064661036 hasConcept C121332964 @default.
- W2064661036 hasConcept C134018914 @default.
- W2064661036 hasConcept C145148216 @default.
- W2064661036 hasConcept C149635348 @default.
- W2064661036 hasConcept C161790260 @default.
- W2064661036 hasConcept C163638829 @default.
- W2064661036 hasConcept C178790620 @default.
- W2064661036 hasConcept C185039092 @default.
- W2064661036 hasConcept C185592680 @default.
- W2064661036 hasConcept C198291218 @default.
- W2064661036 hasConcept C207114421 @default.
- W2064661036 hasConcept C2777270887 @default.
- W2064661036 hasConcept C2778541603 @default.
- W2064661036 hasConcept C2779852509 @default.
- W2064661036 hasConcept C2780378348 @default.
- W2064661036 hasConcept C32909587 @default.
- W2064661036 hasConcept C41008148 @default.
- W2064661036 hasConcept C50515024 @default.
- W2064661036 hasConcept C58312451 @default.
- W2064661036 hasConcept C71240020 @default.
- W2064661036 hasConcept C71924100 @default.
- W2064661036 hasConcept C8010536 @default.
- W2064661036 hasConceptScore W2064661036C115624301 @default.
- W2064661036 hasConceptScore W2064661036C115645028 @default.
- W2064661036 hasConceptScore W2064661036C120665830 @default.
- W2064661036 hasConceptScore W2064661036C121332964 @default.
- W2064661036 hasConceptScore W2064661036C134018914 @default.
- W2064661036 hasConceptScore W2064661036C145148216 @default.
- W2064661036 hasConceptScore W2064661036C149635348 @default.
- W2064661036 hasConceptScore W2064661036C161790260 @default.
- W2064661036 hasConceptScore W2064661036C163638829 @default.
- W2064661036 hasConceptScore W2064661036C178790620 @default.
- W2064661036 hasConceptScore W2064661036C185039092 @default.
- W2064661036 hasConceptScore W2064661036C185592680 @default.
- W2064661036 hasConceptScore W2064661036C198291218 @default.
- W2064661036 hasConceptScore W2064661036C207114421 @default.
- W2064661036 hasConceptScore W2064661036C2777270887 @default.
- W2064661036 hasConceptScore W2064661036C2778541603 @default.
- W2064661036 hasConceptScore W2064661036C2779852509 @default.
- W2064661036 hasConceptScore W2064661036C2780378348 @default.
- W2064661036 hasConceptScore W2064661036C32909587 @default.
- W2064661036 hasConceptScore W2064661036C41008148 @default.
- W2064661036 hasConceptScore W2064661036C50515024 @default.
- W2064661036 hasConceptScore W2064661036C58312451 @default.
- W2064661036 hasConceptScore W2064661036C71240020 @default.
- W2064661036 hasConceptScore W2064661036C71924100 @default.
- W2064661036 hasConceptScore W2064661036C8010536 @default.